Method: input vs recall
Duolingo is recall-first: it asks you to produce a word or sentence from memory and tells you whether you got it right. LibroAI is input-first: it surrounds you with the target language and gives you a tool (tap-to-translate) to handle gaps in real time.
Both are valid. Research on second-language acquisition (Krashen, Nation) tends to credit massive comprehensible input for fluency gains, while spaced recall drives short-term retention. Neither app does both well; they're optimized for different parts of the learning curve.